What is the default power-on voltage for LDO4?

As mentioned in SOM datasheet, LDO4 is by default set to 1.2V in PMIC OTP and on power-up it will be 1.2V.

And after booting, it can be configured between 1.2V and 3.3V through software (FSBL).

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Please find the detailed product information here:
ZU49/ZU39/ZU29DR RFSoC System on Module