Can SDIO be used as GPIO? How to change the SDIO voltage to 1.8V or 3.3V?

The IO level of SDIO pins can be changed even when they are configured as GPIOs. Voltage selection for SD2 bank is facilitated through SD_VSEL pin.

Note: IO level of SDIO pins changes to 1.8V if the status of SD_VSEL pin is high and 3.3V when SD_VSEL pin is low.

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Please find the detailed product information here:
i.MX 93 OSM System on Module